Atoms rearrange, and none are lost

Years 9–12Stage 5 to Stage 6Move it

In a chemical reaction, atoms rearrange and none is made or destroyed.

Demonstration: a simplified modelNot to scale1 · The set-up

A plastic bottle, sealed with its cap, stands on a balance reading 20.00 g. It holds hydrogen peroxide solution, with a catalyst at the bottom. Molecules drawn: hydrogen peroxide, 4; water, 0; oxygen, 0, all inside the bottle. Atoms drawn in the bottle now: 8 hydrogen and 8 oxygen; at the start: 8 hydrogen and 8 oxygen.

Safety: a sealed bottle holds gas under pressure. Wear eye protection.

Hydrogen peroxide solution and a catalyst, in a sealed bottle on a balance.

  1. Cap
  2. Plastic bottle
  3. Hydrogen peroxide solution
  4. Catalyst
  5. Balance

Key Small white circles: hydrogen atoms, H. Larger red circles: oxygen atoms, O. Dashed arrow: the way out of the open bottle. A shaded row with a dashed outline: the two sides of the equation differ.

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The idea, step by step

Not to scale

  1. A plastic bottle, sealed with its cap, stands on a balance reading 20.00 g. All the hydrogen peroxide drawn has broken down, so the liquid is water, with the catalyst at the bottom. Molecules drawn: water, 4; oxygen, 2, all inside the bottle. Atoms drawn in the bottle now: 8 hydrogen and 8 oxygen; at the start: 8 hydrogen and 8 oxygen.
    2 · Atoms rearrangedThe same atoms joined up again as water and oxygen: the bubbles. None made, none lost.1 Cap · 2 Oxygen gas · 3 Plastic bottle · 4 Water · 5 Catalyst · 6 Balance
  2. A plastic bottle with its cap off stands on a balance reading 19.72 g. All the hydrogen peroxide drawn has broken down, so the liquid is water, with the catalyst at the bottom. Molecules drawn: water, 4; oxygen inside the bottle, 0; oxygen gone out of the open neck, 2. Atoms drawn in the bottle now: 8 hydrogen and 4 oxygen; at the start: 8 hydrogen and 8 oxygen.
    3 · Cap offCap off, the oxygen escapes. Gas has mass, so the reading falls by the oxygen's mass.1 Oxygen gas · 2 Plastic bottle · 3 Water · 4 Catalyst · 5 Balance
  3. The equation as written has 1 of H₂O₂ on the reactant side, and 1 of H₂O and 1 of O₂ on the product side, each drawn as that many molecules. Reactant side: 2 hydrogen and 2 oxygen atoms. Product side: 2 hydrogen and 3 oxygen atoms. Not balanced.
    4 · One of eachWith one of each, the products have an extra oxygen atom from nowhere, so this is wrong.1 Subscript
  4. The equation as written has 2 of H₂O₂ on the reactant side, and 2 of H₂O and 1 of O₂ on the product side, each drawn as that many molecules. Reactant side: 4 hydrogen and 4 oxygen atoms. Product side: 4 hydrogen and 4 oxygen atoms. Balanced.
    5 · BalancedTwo H₂O₂ make two H₂O and one O₂: the same atoms, but two molecules become three.1 Coefficient · 2 Subscript
  5. The equation as written has 2 of H₂O₂ on the reactant side, and 2 of H₂O and 1 of O₂ on the product side, each drawn as that many molecules. Reactant side: 4 hydrogen and 4 oxygen atoms. Product side: 4 hydrogen and 4 oxygen atoms. Balanced.
    6 · Coefficients, not subscriptsA coefficient counts molecules; a subscript is part of the formula: H₂O₂ is not H₂O.1 Coefficient · 2 Subscript
  6. The equation as written has 2 of H₂O₂ on the reactant side, and 2 of H₂O and 1 of O₂ on the product side, each drawn as that many molecules. Reactant side: 4 hydrogen and 4 oxygen atoms. Product side: 4 hydrogen and 4 oxygen atoms. Balanced.
    7 · The ratioThe coefficients give the ratio: two H₂O₂ make two H₂O and one O₂. No mass is lost.1 Coefficient · 2 Subscript

The bottle at each moment of the run, sealed or open as you chose

MomentH₂O₂ molecules drawnH₂O molecules drawnO₂ molecules in the bottleO₂ molecules gone from the bottleBalance reading (g)
At the start400020.00
First two H₂O₂ broken down221020.00
First O₂ at the top of the bottle221020.00
Last two H₂O₂ broken down042020.00
Second O₂ at the top of the bottle042020.00
With a learner

Three questions to ask

  1. What happens to the atoms of hydrogen peroxide when it breaks down?
  2. What does the balance weigh, and what could change its reading?
  3. How can you tell whether an equation is balanced?

What to expect

Many learners think a gas has no mass, and count molecules instead of atoms when they balance an equation.

What to try next

Open a practical in Try it in the Lab, above, to test the same law with vinegar and bicarbonate of soda in a sealed bottle, or with magnesium burning in a crucible.

About this model

What is simplified

  • Not to scale: the molecules are drawn many billions of times larger than real ones, and only four hydrogen peroxide molecules are drawn. Each stands for a huge number of real ones (billions of billions), and the water the hydrogen peroxide is dissolved in is not drawn.
  • Atoms are drawn as circles, oxygen larger than hydrogen as it is, and further apart than in a real molecule so each can be seen. Water's bent shape is drawn at its real angle; hydrogen peroxide is drawn flat, though a real molecule is twisted.
  • The balance weighs the whole bottle and its contents, never the equation. The equation's coefficients change only the equation and its count of atoms.
  • The balance starts at a round reading for the model; what matters is how the reading changes. The model's bottle holds a small amount of dilute hydrogen peroxide, the strength sold in pharmacies.
  • Each oxygen molecule drawn stands for half the oxygen made, so in the open bottle the reading falls in two steps. A real reading falls smoothly as the gas escapes, and a little oxygen stays dissolved.
  • The run shows the order of events, not how long they take: a real bottle fizzes for minutes. The catalyst, manganese dioxide powder, speeds up the breakdown and is not used up, so it is not in the equation.
  • A sealed plastic bottle can bulge a little as the gas builds up; the model's bottle keeps its shape, so the air it pushes aside, and the reading, stay the same.

Numbers and their sources

Review

Demonstration: a simplified model. Checked against its written sources, 26 September 2026. Not reviewed by a qualified teacher.

Curriculum references

SC5-RXN-01SC5-WS-06CH11-9CH11-10CH-11-02CH-11-03INS11-11AC9S9U07AC9S10U07

Reference, not a verified alignment.

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